Journal of Petrochemical Universities
Home
About Journal
Overview
Editorial Department
Contact Us
Policies
Editorial Policy
Publishing Ethics
Open Access
Administrative Policies & Others
Guide for Authors
Submission Guidelines
Download Center
Editorial Board
JLPU Homepage
Sponsor Homepage
中文
Journals
Publication Years
Keywords
Search within results
(((Mo Zhousheng[Author]) AND 1[Journal]) AND year[Order])
AND
OR
NOT
Title
Author
Institution
Keyword
Abstract
PACS
DOI
Please wait a minute...
For Selected:
Download Citations
EndNote
Ris
BibTeX
Toggle Thumbnails
Select
Effect of Oil Displacement Agent on Process of Low Temperature Catalytic Oxidation of Heavy Oil
Zhou Guangjian, Qin Yucai, Li Qiang, Mo Zhousheng, Zhang Xiaotong, Song Lijuan
Abstract
(
627
)
PDF
(4233KB)(
452
)
Knowledge map
In order to improve the safety of air flooding and quality of heavy oil, static oxidation experiments were conducted to research the effect of oil displacement agent on the catalytic low temperature oxidation (CLTO) of heavy oil. The results showed that the oil displacement agent could accelerate the oxygen consumption rate, and especially the effect of NaOH and PAM on oxygen consumption rate were obvious. Saturates, aromatics, resins and asphaltenes (SARA) analysis and experiments using oil displacement agent were preformed to study the effect of oil displacement agent on the crude oil components. Saturates and aromatics were converted to resins and asphaltenes during low temperature oxidation (LTO), and the addition of Fe3O4 nanoparticles could reverse this change. This study can provide guidelines to select of oil displacement agent, improve the safety and increase the application of air flooding technology.
2016, 29 (4): 1-6.
DOI:
10.3969/j.issn.1006-396X.2016.04.001
Select
Effect of Promoters on Performance of CuOZnOZrO2 Catalyst Prepared for CO2 Hydrogenation to Methanol
Li Peipei, Qin Yucai, Li Qiang, Mo Zhousheng, Zhang Yuanyuan, Song Lijuan
Abstract
(
601
)
PDF
(1940KB)(
470
)
Knowledge map
CuOZnOZrO2 catalyst was modified by combustion method, using Al2O3, CeO2, NiO metal oxides as promoters. The effects of Al2O3, CeO2, NiO on phase composition and catalyst structure were illuminated by using Xraydiffraction (XRD), temperatureprogrammed reduction ofhydrogen(H2TPR), temperatureprogrammed desorption of hydrogen (H2TPD) and carbon dioxide (CO2TPD) techniques. And the effects of the three chosen promoters on catalytic performance for CO2 hydrogenation to methanol were studied in a fixedbed plug flow reactor. The results indicated that the three promotes of Al2O3, CeO2, NiO all contributed to improving theactivity of catalysts and CeO2modified catalyst had best catalytic performance. Moreover, the three promotes all could inhibit CuO crystal grain growth and improve the dispersion of CuO, which could benefit the reduction of catalysts and H2 adsorptiondissociation. Besides that, the three metal oxides could modulate the intensity amount of basic sites on the catalyst surface in different degrees. Comparing with NiOmodified catalyst, CeO2modified catalyst and Al2O3 modified catalyst both possessed higher basic intensity and more basia sites, which led to CO2 adsorptionactivation easily.
2016, 29 (3): 12-17.
DOI:
10.3969/j.issn.1006-396X.2016.03.003
Select
Infrared Spectroscopy Study on Catalytic Conversion of Thiophene and Thiophane over Rare Ions Modified Y Zeolites
Zhang Chang,Qin Yucai,Mo Zhousheng,et al
Abstract
(
377
)
PDF
(3678KB)(
539
)
Knowledge map
Surface acidities of the Y zeolites(NaY, HY, LCeY and HRSY3) were characterized by temperatureprogrammed desorption of ammonia(NH3TPD) and in situ fourier transform Infrared Spectroscopy using pyridine as probe molecule (PyFTIR). The adsorption and catalytic transformation behaviors of sulfides on Y zeolites modified by rare ions were studied by in situ fourier transform Infrared Spectroscopy (in situ FTIR) technology using thiophene andthiophane as the probe molecules, respectively. The results indicated that thiophene molecules protonated upon the strong Brnsted acid sites of the zeolites at room temperature, then protonated products could further oligomerize. The synergy between L acid sites (included Ce species andnonframework aluminum species) and Brnsted (B) acid sites was favorable to oligomerization reaction of Thiophene, however, there were no reactions of thiophane over NaY, HY and REY.
2015, 28 (2): 13-18.
DOI:
10.3969/j.issn.1006-396X.2015.02.003